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Re: Si pin xrf ..1st go

taray singh
 


Here is an assortment of wrist plates of various sizes and color.
They are essentially made of titanium or stainless steel alloy

Taray


On Sunday, October 4, 2020, 12:23:37 AM GMT+8, <geoelectronics@...> wrote:


Very good work Taray, thank you.

When you want to explain a photo of a scan better by adding charts, lines, pictures
or text,? on the DPPMCA program bring up the file of the scan then go to FILE
and select "Capture Plot". When clicked on, the screen will be saved in your clipboard similar to "Ctrl+C" function.? Open your photo program (I use PAINT) and simply drop the screen into the edit box by "Ctrl+V" or there should be a "Paste" icon on the photo program controls.?

Now you can do the editing like label peaks, draw reference lines and add text.

If there is a popup on the scan, such as Peak Search, for some reason that won't go along with the plot, so try "Ctrl+PrtSc" for nearly the same effect.

Geo

----- Original Message -----
From: taray singh via groups.io <sukhjez@...>
To: [email protected], [email protected]
Sent: Sat, 03 Oct 2020 01:24:55 -0400 (EDT)
Subject: Re: [XRF] Si pin xrf ..1st go



Hi guys
I have compleed my analysis for the knee implant
The body of the implant(both upper and lower joint surfaces are identical
They consist of Titanium,Cr,Co and molyddenum? alloy
I could not find? any Ni {Nickel can cause allergic reactions)which is good.

As for the stem(shank),I had to repeat a longer scan.
The previous one was not long enough for the low count rate.
It is mainly titanium
The smaller peaks on the right do not fit into any shell I know.
This stem is not stainless steal like I expected
Taray


On Saturday, October 3, 2020, 11:27:20 AM GMT+8, taray singh via groups.io <sukhjez@...> wrote:


Here is another pic I left out.
The? previous joint surface pic is for the femoral end(upper)
This one is for the lower/golden end (tibial) attached to the stem.




Re: FAQ- Why the unique X-Ray peaks from atoms?

 

开云体育

Most excellent explanation of the concept of fluorescence as it relates to XRF, Geo.? Similar concepts apply to all methods of spectroscopy, whether in the RF, infrared, visible spectrum, UV, X-ray, and gamma photons.? It also plays a role in why red LEDs are red, green LEDs are green, etc.? It all boils down to “characteristic emissions” for different elements.

?

While the concept of using a higher-energy (i.e., higher frequency/shorter wavelength) “exciter” to elicit a lower-energy photon – the concept behind using a higher-energy beta-emitter or gamma emitter to produce a lower-energy X-ray – the process can work in reverse.? I’ve seen plastic cards used which glow in the visible spectrum to “detect” the presence of an infrared laser beam.? Initially I didn’t understand how a low energy/low frequency IR beam could produce a higher-energy ‘response’ in the visible spectrum.? Then I remembered my ham radio concepts of using diodes to double the frequency of an incident input wave.?? Using the same physics, an ‘invisible’ light source (at least to humans) of 1100 nanometers in the infrared spectrum doubles in frequency to correspond to a half-wavelength of 550 nm, which is in the green-portion of the human perception of the visible spectrum.? Many laser diodes use frequency doubling to get the desired wavelength, but it comes at a cost… when you double the frequency, the power drops proportionally.? There are numerous “hacks” out there to dissect a Blue-ray DVD player or DVD “burner” to extract the laser diode, remove the optical frequency-doubler, and get a higher-power infrared laser.

?

Thanks again for the physics lesson, Geo.

?

Ken

?

From: GEOelectronics@...
Sent: Saturday, October 3, 2020 12:10 PM
To: [email protected]
Subject: [XRF] FAQ- Why the unique X-Ray peaks from atoms?

?

PART-1 Definitions. Some are specific to the XRF sub-discipline.

Practicing XRF is what we do and discuss on this chat board.?
For those who are reading but aren't practicing XRF techniques yet, lets lay out some of the theory behind XRF-

First the initials stand for X-Ray Fluorescence.?
A few definitions of the noun fluorescence in layman is "shine" another is "glow"..?
For our our purposes the definition of General Science is a little more detailed:


1.??? The giving off of light by a substance when it is exposed to electromagnetic radiation, such as visible light or x-rays. As long as electromagnetic radiation continues to bombard the substance, electrons in the fluorescent material become excited but return very quickly to lower energy, giving off light, always of the same frequency. Fluorescent dyes are often used in microscopic imaging, where different dyes can penetrate and illuminate different parts of the sample being examined, helping to distinguish its structures.

Compare?

2.??? The light produced in this way

So in very basic terms, the "F" in XRF is to shine by means of energy transfer at an atomic level, and the XR part defines? the "light" we detect as being X-Rays. To make the atom fluoresce X-Rays can be done by a number of means, not always having to do with applying X-Rays to the sample. The external energy can come from an electromagnetic source of from charged particles like Alpha Particles and fast electrons. A lot of the XRF we look at are excited by the energy ejected from the nucleus of a newly created element a result of radioactive decay of its parent element. This latter X-Ray and Gamma Ray from the daughter is usually immediate, but can be delayed, sometime much longer. Such daughter elements are appended with the small letter "m" for metastable.
Check out Cs-137/Ba-137m decay scheme. Ba-137m has a half-life (T/2) of 2.55 minutes.

Remember radio waves, microwaves, infrared, visible light, ultraviolet light, X-Rays and Gamm Rays are all "light"- simply electromagnetic radiation of different energy levels..

In this practice we consider X-Rays as being electromagnetic energy being formed from the electron shell of an individual atom, while Gamma Rays originate within an atom's nucleus. Things will be a simpler in the long run if we all consider "Radioactive Decay" the? process that changes parent element to a different element# by changing the proton# in an atoms nucleus. Beta and Alpha decay are the most common, but there are many others.
Once the element has changed to it's new nucleus, there are secondary emissions from that element's nucleus- these include the Gamma Rays and the production of XRF from the daughter product's electron shells.

A very obvious example is the major radioactive check disc we use for calibrating XRF systems: Fe-55. It decays by Electron-Capture (EC) to Mn-55. If we apply an external energy to stable Fe, we get back the XRF energy of Iron Ka1= 6.40 keV (there are others too). If we turn off the external exciter and test radioactive Fe-55, on our instruments, we see X-Rays of the daughter which is 5.90keV. There's no mistaking the two with a Si-PIN or other high resolution detector.

Highlight- natural X-Rays from radioactive element are of the daughter, induced X-Rays of stable elements is of that element.

Important! Keep the above in mind as we discuss XRF.



Let's stop here for discussion, we can add more definitions later via the edit function.

Geo

?


Re: Si pin xrf ..1st go

 

Very good work Taray, thank you.

When you want to explain a photo of a scan better by adding charts, lines, pictures
or text,? on the DPPMCA program bring up the file of the scan then go to FILE
and select "Capture Plot". When clicked on, the screen will be saved in your clipboard similar to "Ctrl+C" function.? Open your photo program (I use PAINT) and simply drop the screen into the edit box by "Ctrl+V" or there should be a "Paste" icon on the photo program controls.?

Now you can do the editing like label peaks, draw reference lines and add text.

If there is a popup on the scan, such as Peak Search, for some reason that won't go along with the plot, so try "Ctrl+PrtSc" for nearly the same effect.

Geo

----- Original Message -----
From: taray singh via groups.io <sukhjez@...>
To: [email protected], [email protected]
Sent: Sat, 03 Oct 2020 01:24:55 -0400 (EDT)
Subject: Re: [XRF] Si pin xrf ..1st go



Hi guys
I have compleed my analysis for the knee implant
The body of the implant(both upper and lower joint surfaces are identical
They consist of Titanium,Cr,Co and molyddenum? alloy
I could not find? any Ni {Nickel can cause allergic reactions)which is good.

As for the stem(shank),I had to repeat a longer scan.
The previous one was not long enough for the low count rate.
It is mainly titanium
The smaller peaks on the right do not fit into any shell I know.
This stem is not stainless steal like I expected
Taray


On Saturday, October 3, 2020, 11:27:20 AM GMT+8, taray singh via groups.io <sukhjez@...> wrote:


Here is another pic I left out.
The? previous joint surface pic is for the femoral end(upper)
This one is for the lower/golden end (tibial) attached to the stem.




FAQ- Why the unique X-Ray peaks from atoms?

 

PART-1 Definitions. Some are specific to the XRF sub-discipline.

Practicing XRF is what we do and discuss on this chat board.?
For those who are reading but aren't practicing XRF techniques yet, lets lay out some of the theory behind XRF-

First the initials stand for X-Ray Fluorescence.?
A few definitions of the noun fluorescence in layman is "shine" another is "glow"..?
For our our purposes the definition of General Science is a little more detailed:

  1. The giving off of light by a substance when it is exposed to electromagnetic radiation, such as visible light or x-rays. As long as electromagnetic radiation continues to bombard the substance, electrons in the fluorescent material become excited but return very quickly to lower energy, giving off light, always of the same frequency. Fluorescent dyes are often used in microscopic imaging, where different dyes can penetrate and illuminate different parts of the sample being examined, helping to distinguish its structures.

    Compare?

  2. The light produced in this way
So in very basic terms, the "F" in XRF is to shine by means of energy transfer at an atomic level, and the XR part defines? the "light" we detect as being X-Rays. To make the atom fluoresce X-Rays can be done by a number of means, not always having to do with applying X-Rays to the sample. The external energy can come from an electromagnetic source of from charged particles like Alpha Particles and fast electrons. A lot of the XRF we look at are excited by the energy ejected from the nucleus of a newly created element a result of radioactive decay of its parent element. This latter X-Ray and Gamma Ray from the daughter is usually immediate, but can be delayed, sometime much longer. Such daughter elements are appended with the small letter "m" for metastable.
Check out Cs-137/Ba-137m decay scheme. Ba-137m has a half-life (T/2) of 2.55 minutes.

Remember radio waves, microwaves, infrared, visible light, ultraviolet light, X-Rays and Gamm Rays are all "light"- simply electromagnetic radiation of different energy levels..

In this practice we consider X-Rays as being electromagnetic energy being formed from the electron shell of an individual atom, while Gamma Rays originate within an atom's nucleus. Things will be a simpler in the long run if we all consider "Radioactive Decay" the? process that changes parent element to a different element# by changing the proton# in an atoms nucleus. Beta and Alpha decay are the most common, but there are many others.
Once the element has changed to it's new nucleus, there are secondary emissions from that element's nucleus- these include the Gamma Rays and the production of XRF from the daughter product's electron shells.

A very obvious example is the major radioactive check disc we use for calibrating XRF systems: Fe-55. It decays by Electron-Capture (EC) to Mn-55. If we apply an external energy to stable Fe, we get back the XRF energy of Iron Ka1= 6.40 keV (there are others too). If we turn off the external exciter and test radioactive Fe-55, on our instruments, we see X-Rays of the daughter which is 5.90keV. There's no mistaking the two with a Si-PIN or other high resolution detector.

Highlight- natural X-Rays from radioactive element are of the daughter, induced X-Rays of stable elements is of that element.

Important! Keep the above in mind as we discuss XRF.



Let's stop here for discussion, we can add more definitions later via the edit function.

Geo


Re: Si pin xrf ..1st go

taray singh
 


Hi guys
I have compleed my analysis for the knee implant
The body of the implant(both upper and lower joint surfaces are identical
They consist of Titanium,Cr,Co and molyddenum? alloy
I could not find? any Ni {Nickel can cause allergic reactions)which is good.

As for the stem(shank),I had to repeat a longer scan.
The previous one was not long enough for the low count rate.
It is mainly titanium
The smaller peaks on the right do not fit into any shell I know.
This stem is not stainless steal like I expected
Taray

On Saturday, October 3, 2020, 11:27:20 AM GMT+8, taray singh via groups.io <sukhjez@...> wrote:


Here is another pic I left out.
The? previous joint surface pic is for the femoral end(upper)
This one is for the lower/golden end (tibial) attached to the stem.


Re: Si pin xrf ..1st go

taray singh
 

Here is another pic I left out.
The? previous joint surface pic is for the femoral end(upper)
This one is for the lower/golden end (tibial) attached to the stem.


Re: Si pin xrf ..1st go

taray singh
 

Hi guys
These are for the "golden" knee implants
Pics are for joint surface and the shank.
Seems not use easy at one quick look.
My "provisional diagnosis" may be wrong?
There could be some spectral overlay.
Need? time to study carefully.
Like Dude says,I don't want to create hypothesis
A good reference is the knee implant pdf file I gave earlier
?
Taray


Re: Trinitite

 

"On Fri, Oct 2, 2020 at 11:10 AM, Randall Buck wrote:
Yes, for the principal lines.
Neutrons do not influence electrons directly but they do alter the statistical distribution
of the protons.
notice the red and yellow are not a perfect match at all energies.

Randall"


Well... this is looking at two different isotopes of the same element, the major lines are that elements XRF and are the same for any of it's isotopes. The minor lines can be accounted for by the mounting substrate of the sample and the different decay schemes of the particular isotope.??

The Ka, La etc lines of a particular element are listed only once, not by isotope.


Re: Si pin xrf ..1st go

 

开云体育

No one is gunna put that God awful thing in ME

Dud

From: [email protected] [mailto:[email protected]] On Behalf Of taray singh via groups.io
Sent: Friday, October 2, 2020 7:37 AM
To: [email protected]
Subject: Re: [XRF] Si pin xrf ..1st go

?



Yet to scan

The shaft is stainless steel

Gold color is Ti??and Zr?

Can be used as an Olympic torch??if??needed

?

?



On 2 Oct 2020, at 8:51 PM, GEOelectronics@... wrote:

?

Thanks for those pictures. The one on the right with the long shank looks more like the one I am familiar with. The bearing plate can be changed with small incision, like changing brake pads on a car.

?

Geo

?

?


From: "taray singh via groups.io" <sukhjez@...>
To: [email protected]
Sent: Friday, October 2, 2020 6:30:12 AM
Subject: Re: [XRF] Si pin xrf ..1st go

?

?

Dude

Good advice.

With regard to 2048 gain,I will put on hold for now

Need to recalibrate to do so.

Need time to familiarize software first.

Thanks for the apron analysis

It's a composite rubberized lead apron.

Most likely homogenous

It will attenuate medical 120 kev x rays according to lead equivalent values.

Since it is close to the skin,the xrf esp from Sn to tissue is a concern.

Radiation is stochastic in nature.

Nuclear medicine departments apron are different.

?

Regarding my knee implant analysis above,my ortho colleague agrees it is?

CoCrMb .He was probably testing me.

I have some new implants awaiting xrf

Welcome to Medical XrF

Taray

?

?

On Friday, October 2, 2020, 04:37:52 AM GMT+8, Dude <dfemer@...> wrote:

?

Taray,

Attached is a look at the original X-ray apron file you sent (Apron Dud.jpg). This is the same as Apron 1 and is a Pb Sn construction. Apron 2 is also a Pb Sn apron.

The F7F27 .jpeg you sent is looks to be Apron 2 which is of a Pb Sn construction not Bi Sn.

?

Pb La1 10.55 keV

Pb Lb1? 12.61

Pb Lg1? 14.76

?

Bi La1 10.83 keV

Bi Lb1? 13.02

Bi Lg1? 15.24

?

Close together lines can create interpretation problems especially in noisy low resolution data. The use of a computer pick and pre labeled lines for ID is a bad idea and even worse is a preconceived notion of what you are expecting. The data tells you what it is not the other way around. A hypothesis is great, but test and verify it.

Note that your using a 1024 channel conversion gain over an energy range of 133 keV / 1024 channels or 0.13 keV/channel.

The energy separation between Pb and Bi La1 is only 0.38 keV or 3 channels and a Si detector has a FWHM resolution of about 0.250 keV at the Pb La1. The Si detector efficiency falls off very rapidly above 30 keV or so it would make better sense to calibrate 0 to 66 keV using a 2048 conversion gain. That would give you 0.03 keV/channel and allows you to do a AM-241 cal check as well.

I’d also recommend doing longer count times to better define the peaks and to see the confirming lower yield peaks.

Dud

?

From: [email protected] [mailto:[email protected]] On Behalf Of taray singh via groups.io
Sent: Tuesday, September 29, 2020 4:22 AM
To: [email protected]
Subject: Re: [XRF] Si pin xrf ..1st go

?

Here is the x ray apron file.
Taray

?


Re: Trinitite

 

Yes, for the principal lines.
Neutrons do not influence electrons directly but they do alter the statistical distribution
of the protons.
notice the red and yellow are not a perfect match at all energies.

Randall

----- Original Message -----
From: GEOelectronics@...
To: [email protected]
Sent: Thu, 01 Oct 2020 10:51:49 -0700 (PDT)
Subject: Re: [XRF] Trinitite

Here's a graphic illustration that XRF energies go by the # of Protons in the nucleus, regardless of the # of Neutron in it.

Change the # Protons = different? element = different XRF energies.

Geo


Re: Si pin xrf ..1st go

 

开云体育

Sounds good Taray. Keep those weird metal pieces coming we never get to see stuff like that. I wonder what dental implants look like.

Dud

?

From: [email protected] [mailto:[email protected]] On Behalf Of taray singh via groups.io
Sent: Friday, October 2, 2020 4:30 AM
To: [email protected]
Subject: Re: [XRF] Si pin xrf ..1st go

?

?

Dude

Good advice.

With regard to 2048 gain,I will put on hold for now

Need to recalibrate to do so.

Need time to familiarize software first.

Thanks for the apron analysis

It's a composite rubberized lead apron.

Most likely homogenous

It will attenuate medical 120 kev x rays according to lead equivalent values.

Since it is close to the skin,the xrf esp from Sn to tissue is a concern.

Radiation is stochastic in nature.

Nuclear medicine departments apron are different.

?

?

Regarding my knee implant analysis above,my ortho colleague agrees it is?

CoCrMb .He was probably testing me.

I have some new implants awaiting xrf

Welcome to Medical XrF

Taray

?

?

?

On Friday, October 2, 2020, 04:37:52 AM GMT+8, Dude <dfemer@...> wrote:

?

?

Taray,

Attached is a look at the original X-ray apron file you sent (Apron Dud.jpg). This is the same as Apron 1 and is a Pb Sn construction. Apron 2 is also a Pb Sn apron.

The F7F27 .jpeg you sent is looks to be Apron 2 which is of a Pb Sn construction not Bi Sn.

?

Pb La1 10.55 keV

Pb Lb1? 12.61

Pb Lg1? 14.76

?

Bi La1 10.83 keV

Bi Lb1? 13.02

Bi Lg1? 15.24

?

Close together lines can create interpretation problems especially in noisy low resolution data. The use of a computer pick and pre labeled lines for ID is a bad idea and even worse is a preconceived notion of what you are expecting. The data tells you what it is not the other way around. A hypothesis is great, but test and verify it.

Note that your using a 1024 channel conversion gain over an energy range of 133 keV / 1024 channels or 0.13 keV/channel.

The energy separation between Pb and Bi La1 is only 0.38 keV or 3 channels and a Si detector has a FWHM resolution of about 0.250 keV at the Pb La1. The Si detector efficiency falls off very rapidly above 30 keV or so it would make better sense to calibrate 0 to 66 keV using a 2048 conversion gain. That would give you 0.03 keV/channel and allows you to do a AM-241 cal check as well.

I’d also recommend doing longer count times to better define the peaks and to see the confirming lower yield peaks.

Dud

?

From: [email protected] [mailto:[email protected]] On Behalf Of taray singh via groups.io
Sent: Tuesday, September 29, 2020 4:22 AM
To: [email protected]
Subject: Re: [XRF] Si pin xrf ..1st go

?

Here is the x ray apron file.
Taray


Re: Trinitite

 

So here are the steps.

A) Take reading of a calibrated sample.
B) Take reading of unknown sample
C) Compare the two readings, calculate the ratio.
D) Apply that ratio to the certified quantity in calibrated sample
E) Determine the size of the detector (5mm X 5mm)
F)? Calculate the weight of the parent by? your measured activity (D) (below)
G) Calculate the Molar content (below)
H) Calculate the # of atoms from the Molar content (below) per surface area of the probe (E)

All without higher math or lookup tables.
Pu_max_5mmx5mm-PUB.png


Re: Trinitite

 

Quantification- the hard part.

Red Trinitite, per 25mm^2 (5mm x 5mm)

Pu_max_5mmx5mm.png



Re: Si pin xrf ..1st go

taray singh
 

开云体育


Yet to scan

The shaft is stainless steel

Gold color is Ti??and Zr?

Can be used as an Olympic torch??if??needed




On 2 Oct 2020, at 8:51 PM, GEOelectronics@... wrote:

?
Thanks for those pictures. The one on the right with the long shank looks more like the one I am familiar with. The bearing plate can be changed with small incision, like changing brake pads on a car.

Geo



From: "taray singh via groups.io" <sukhjez@...>
To: [email protected]
Sent: Friday, October 2, 2020 6:30:12 AM
Subject: Re: [XRF] Si pin xrf ..1st go


Dude
Good advice.
With regard to 2048 gain,I will put on hold for now
Need to recalibrate to do so.
Need time to familiarize software first.
Thanks for the apron analysis
It's a composite rubberized lead apron.
Most likely homogenous
It will attenuate medical 120 kev x rays according to lead equivalent values.
Since it is close to the skin,the xrf esp from Sn to tissue is a concern.
Radiation is stochastic in nature.
Nuclear medicine departments apron are different.


Regarding my knee implant analysis above,my ortho colleague agrees it is?
CoCrMb .He was probably testing me.
I have some new implants awaiting xrf
Welcome to Medical XrF
Taray



On Friday, October 2, 2020, 04:37:52 AM GMT+8, Dude <dfemer@...> wrote:


Taray,

Attached is a look at the original X-ray apron file you sent (Apron Dud.jpg). This is the same as Apron 1 and is a Pb Sn construction. Apron 2 is also a Pb Sn apron.

The F7F27 .jpeg you sent is looks to be Apron 2 which is of a Pb Sn construction not Bi Sn.

?

Pb La1 10.55 keV

Pb Lb1? 12.61

Pb Lg1? 14.76

?

Bi La1 10.83 keV

Bi Lb1? 13.02

Bi Lg1? 15.24

?

Close together lines can create interpretation problems especially in noisy low resolution data. The use of a computer pick and pre labeled lines for ID is a bad idea and even worse is a preconceived notion of what you are expecting. The data tells you what it is not the other way around. A hypothesis is great, but test and verify it.

Note that your using a 1024 channel conversion gain over an energy range of 133 keV / 1024 channels or 0.13 keV/channel.

The energy separation between Pb and Bi La1 is only 0.38 keV or 3 channels and a Si detector has a FWHM resolution of about 0.250 keV at the Pb La1. The Si detector efficiency falls off very rapidly above 30 keV or so it would make better sense to calibrate 0 to 66 keV using a 2048 conversion gain. That would give you 0.03 keV/channel and allows you to do a AM-241 cal check as well.

I’d also recommend doing longer count times to better define the peaks and to see the confirming lower yield peaks.

Dud

?

From: [email protected] [mailto:[email protected]] On Behalf Of taray singh via groups.io
Sent: Tuesday, September 29, 2020 4:22 AM
To: [email protected]
Subject: Re: [XRF] Si pin xrf ..1st go

?

Here is the x ray apron file.
Taray



Re: Si pin xrf ..1st go

 

Thanks for those pictures. The one on the right with the long shank looks more like the one I am familiar with. The bearing plate can be changed with small incision, like changing brake pads on a car.

Geo



From: "taray singh via groups.io" <sukhjez@...>
To: [email protected]
Sent: Friday, October 2, 2020 6:30:12 AM
Subject: Re: [XRF] Si pin xrf ..1st go


Dude
Good advice.
With regard to 2048 gain,I will put on hold for now
Need to recalibrate to do so.
Need time to familiarize software first.
Thanks for the apron analysis
It's a composite rubberized lead apron.
Most likely homogenous
It will attenuate medical 120 kev x rays according to lead equivalent values.
Since it is close to the skin,the xrf esp from Sn to tissue is a concern.
Radiation is stochastic in nature.
Nuclear medicine departments apron are different.


Regarding my knee implant analysis above,my ortho colleague agrees it is?
CoCrMb .He was probably testing me.
I have some new implants awaiting xrf
Welcome to Medical XrF
Taray



On Friday, October 2, 2020, 04:37:52 AM GMT+8, Dude <dfemer@...> wrote:


Taray,

Attached is a look at the original X-ray apron file you sent (Apron Dud.jpg). This is the same as Apron 1 and is a Pb Sn construction. Apron 2 is also a Pb Sn apron.

The F7F27 .jpeg you sent is looks to be Apron 2 which is of a Pb Sn construction not Bi Sn.

?

Pb La1 10.55 keV

Pb Lb1? 12.61

Pb Lg1? 14.76

?

Bi La1 10.83 keV

Bi Lb1? 13.02

Bi Lg1? 15.24

?

Close together lines can create interpretation problems especially in noisy low resolution data. The use of a computer pick and pre labeled lines for ID is a bad idea and even worse is a preconceived notion of what you are expecting. The data tells you what it is not the other way around. A hypothesis is great, but test and verify it.

Note that your using a 1024 channel conversion gain over an energy range of 133 keV / 1024 channels or 0.13 keV/channel.

The energy separation between Pb and Bi La1 is only 0.38 keV or 3 channels and a Si detector has a FWHM resolution of about 0.250 keV at the Pb La1. The Si detector efficiency falls off very rapidly above 30 keV or so it would make better sense to calibrate 0 to 66 keV using a 2048 conversion gain. That would give you 0.03 keV/channel and allows you to do a AM-241 cal check as well.

I’d also recommend doing longer count times to better define the peaks and to see the confirming lower yield peaks.

Dud

?

From: [email protected] [mailto:[email protected]] On Behalf Of taray singh via groups.io
Sent: Tuesday, September 29, 2020 4:22 AM
To: [email protected]
Subject: Re: [XRF] Si pin xrf ..1st go

?

Here is the x ray apron file.
Taray



Re: Si pin xrf ..1st go

taray singh
 


Dude
Good advice.
With regard to 2048 gain,I will put on hold for now
Need to recalibrate to do so.
Need time to familiarize software first.
Thanks for the apron analysis
It's a composite rubberized lead apron.
Most likely homogenous
It will attenuate medical 120 kev x rays according to lead equivalent values.
Since it is close to the skin,the xrf esp from Sn to tissue is a concern.
Radiation is stochastic in nature.
Nuclear medicine departments apron are different.


Regarding my knee implant analysis above,my ortho colleague agrees it is?
CoCrMb .He was probably testing me.
I have some new implants awaiting xrf
Welcome to Medical XrF
Taray



On Friday, October 2, 2020, 04:37:52 AM GMT+8, Dude <dfemer@...> wrote:


Taray,

Attached is a look at the original X-ray apron file you sent (Apron Dud.jpg). This is the same as Apron 1 and is a Pb Sn construction. Apron 2 is also a Pb Sn apron.

The F7F27 .jpeg you sent is looks to be Apron 2 which is of a Pb Sn construction not Bi Sn.

?

Pb La1 10.55 keV

Pb Lb1? 12.61

Pb Lg1? 14.76

?

Bi La1 10.83 keV

Bi Lb1? 13.02

Bi Lg1? 15.24

?

Close together lines can create interpretation problems especially in noisy low resolution data. The use of a computer pick and pre labeled lines for ID is a bad idea and even worse is a preconceived notion of what you are expecting. The data tells you what it is not the other way around. A hypothesis is great, but test and verify it.

Note that your using a 1024 channel conversion gain over an energy range of 133 keV / 1024 channels or 0.13 keV/channel.

The energy separation between Pb and Bi La1 is only 0.38 keV or 3 channels and a Si detector has a FWHM resolution of about 0.250 keV at the Pb La1. The Si detector efficiency falls off very rapidly above 30 keV or so it would make better sense to calibrate 0 to 66 keV using a 2048 conversion gain. That would give you 0.03 keV/channel and allows you to do a AM-241 cal check as well.

I’d also recommend doing longer count times to better define the peaks and to see the confirming lower yield peaks.

Dud

?

From: [email protected] [mailto:[email protected]] On Behalf Of taray singh via groups.io
Sent: Tuesday, September 29, 2020 4:22 AM
To: [email protected]
Subject: Re: [XRF] Si pin xrf ..1st go

?

Here is the x ray apron file.
Taray


Re: Trinitite

 

开云体育

The Be was used as a neutron reflector which increased the neutron flux during detonation, it also prevented corrosion of the Pu. ?Al was used between the pit and the Be coating to shield the Be from alpha particles which would generate neutrons.

Dud

?

From: [email protected] [mailto:[email protected]] On Behalf Of GEOelectronics@...
Sent: Thursday, October 1, 2020 5:48 PM
To: [email protected]
Subject: Re: [XRF] Trinitite

?

I just scanned the book, there are references to Be, but only that it makes lots of neutrons when exposed to alpha decay (Pu-239). So it wouldn't have been coated with Be. Aluminum foil would have been all that was needed.

?

Geo

?

----- Original Message -----
From: WILLIAM S Dubyk <sdubyk@...>
To: [email protected]
Sent: Thu, 01 Oct 2020 19:30:26 -0400 (EDT)
Subject: Re: [XRF] Trinitite

?


margin-top: 0;
margin-bottom: 0;
}
/*]]>*/

?


That is pretty interesting, they considered either a RaBe or Po source to ensure detonation.

?


Stevee


From: [email protected] <[email protected]> on behalf of Alan Jose <Alan.Jose@...>
Sent: Thursday, October 1, 2020 5:11 PM
To: [email protected] <[email protected]>
Subject: Re: [XRF] Trinitite

?

?


The book was his autobiography (my copy is from May 1989) and he might have included a picture of him holding it. I’ll try and run that down this weekend.?

?

I would do it now but I am at work.?

?

AlanJ?

?



On Oct 1, 2020, at 6:02 PM, Alan Jose <Alan.Jose@...> wrote:

?


No picture available but that information was gleaned from the biography on Luis Alvarez entitled Alvarez from the late eighties. When time permits I’ll look through the book to find the reference. I could be in error as that is from my memory from a book I
read over thirty years ago. Some things stick and some things don’t.?

?

AlanJ

?



On Oct 1, 2020, at 1:11 PM, GEOelectronics@... wrote:

Hi Alan, can you post a link to the Be coating?


Geo

?

?

?


Re: Trinitite

 

开云体育

For some reason I was thinking beryllium coated and then a thin nickel chrome final coating.?

Possibly brain flatulence.?

However it is a well done book and worth re-reading. At that time it was one of my favorites.?

AlanJ?


On Oct 1, 2020, at 7:47 PM, GEOelectronics@... wrote:

I just scanned the book, there are references to Be, but only that it makes lots of neutrons when exposed to alpha decay (Pu-239). So it wouldn't have been coated with Be. Aluminum foil would have been all that was needed.

Geo

----- Original Message -----
From: WILLIAM S Dubyk <sdubyk@...>
To: [email protected]
Sent: Thu, 01 Oct 2020 19:30:26 -0400 (EDT)
Subject: Re: [XRF] Trinitite



That is pretty interesting, they considered either a RaBe or Po source to ensure detonation.


Stevee

From: [email protected] <[email protected]> on behalf of Alan Jose <Alan.Jose@...>
Sent: Thursday, October 1, 2020 5:11 PM
To: [email protected] <[email protected]>
Subject: Re: [XRF] Trinitite
?


The book was his autobiography (my copy is from May 1989) and he might have included a picture of him holding it. I’ll try and run that down this weekend.?

I would do it now but I am at work.?

AlanJ?




On Oct 1, 2020, at 6:02 PM, Alan Jose <Alan.Jose@...> wrote:



No picture available but that information was gleaned from the biography on Luis Alvarez entitled Alvarez from the late eighties. When time permits I’ll look through the book to find the reference. I could be in error as that is from my memory from a book I
read over thirty years ago. Some things stick and some things don’t.?

AlanJ




On Oct 1, 2020, at 1:11 PM, GEOelectronics@... wrote:

Hi Alan, can you post a link to the Be coating?


Geo




Re: Trinitite

 
Edited

I just scanned the book, there are references to Be, but only that it makes lots of neutrons when exposed to alpha decay (Pu-239),? therefore? in the book he says they went to great lengths to keep Be contaminants out during the manufacture. So it wouldn't have been coated with Be. Aluminum foil would have been all that was needed.
?
Geo
?

----- Original Message -----
From: WILLIAM S Dubyk <sdubyk@...>
To: [email protected]
Sent: Thu, 01 Oct 2020 19:30:26 -0400 (EDT)
Subject: Re: [XRF] Trinitite
?
?
?

That is pretty interesting, they considered either a RaBe or Po source to ensure detonation.
?

Stevee

From: [email protected] <[email protected]> on behalf of Alan Jose <Alan.Jose@...>
Sent: Thursday, October 1, 2020 5:11 PM
To: [email protected] <[email protected]>
Subject: Re: [XRF] Trinitite
?
?

The book was his autobiography (my copy is from May 1989) and he might have included a picture of him holding it. I’ll try and run that down this weekend.?
?
I would do it now but I am at work.?
?
AlanJ?

?


On Oct 1, 2020, at 6:02 PM, Alan Jose <Alan.Jose@...> wrote:

?

No picture available but that information was gleaned from the biography on Luis Alvarez entitled Alvarez from the late eighties. When time permits I’ll look through the book to find the reference. I could be in error as that is from my memory from a book I
read over thirty years ago. Some things stick and some things don’t.?
?
AlanJ

?


On Oct 1, 2020, at 1:11 PM, GEOelectronics@... wrote:

Hi Alan, can you post a link to the Be coating?


Geo
?
?
?


Re: Trinitite

 

no worries Alan.

Geo

----- Original Message -----
From: Alan Jose <Alan.Jose@...>
To: [email protected]
Sent: Thu, 01 Oct 2020 19:11:20 -0400 (EDT)
Subject: Re: [XRF] Trinitite


The book was his autobiography (my copy is from May 1989) and he might have included a picture of him holding it. I’ll try and run that down this weekend.?

I would do it now but I am at work.?

AlanJ?



On Oct 1, 2020, at 6:02 PM, Alan Jose <Alan.Jose@...> wrote:


No picture available but that information was gleaned from the biography on Luis Alvarez entitled Alvarez from the late eighties. When time permits I’ll look through the book to find the reference. I could be in error as that is from my memory from a book I read over thirty years ago. Some things stick and some things don’t.?

AlanJ



On Oct 1, 2020, at 1:11 PM, GEOelectronics@... wrote:

Hi Alan, can you post a link to the Be coating?

Geo