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Re: The case of the missing elements


 

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I think you are comparing two different files. One is Allanite the other is Melanocerite, one from

Canada one from Norway.

Send single spectra plots no overlays.

Dud

From: [email protected] [mailto:[email protected]] On Behalf Of Charles David Young
Sent: Friday, February 7, 2020 2:12 PM
To: [email protected]; Mike Loughlin
Subject: [XRF] The case of the missing elements

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I recently picked up a specimen of melanocerite-Ce at the mineral show and did a scan without Am241 by depending on the internal radiation.? I was not surprised to see Th La Ce and Nd in the blue plot.

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Then I wanted to see if I got the same results using Am241 as an additional exciter.? So I carefully moved the specimen just far enough from the detector to allow me to slide in the Am241 jig.? I was careful to keep the same spot on the rock even though it looked quite uniform.

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Curiously I am now getting additional strong Fe and Y peaks in the red plot.? What could account for this?? I am not surprised that the La Ce Nd are lit up as they are.

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I have also attached both .mca files in case one wishes to analyze them.? However, I am not really asking for that.? I would just like to understand why the Am241 lights up the Fe and Y so strongly compared to the internal radiation.? It is kind of a pain to weed through the Am241 background peaks but it appears that I may not get a complete picture with the internal radiation alone.

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Charles

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