I have 2 setups here, both Pi 4 with the RPi Bookworm (from the Raspberry Pi website, using their Raspberry Pi Imager). Same problem on both.
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Pascal AC7N
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edit:
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I just put Bullseye on one of the Pi4s. Scrot works! Gnome Screenshot also works.
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Can anyone confirm that Bookworm killed the ability to screenshot?
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Pascal AC7N