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Re: Another battery question


 

Lost a reply on the phone...let's try this again on the laptop...

With respect, Jerry, "common usage" depends on the group being surveyed.? For the general public, I agree that "lithium ion", "Lithium polymer", and LiCoO are used interchangeably.? It's like saying all capacitors are electrolytic.? In the marine world, lithium ion specifically means LFP/LiFePO4.? In research and transportation, lithium Ion means the family and one has to identify the chemistry being discussed.? Even within specific chemistries, there can be 'power cells' or 'energy cells', and some LFP are doped with yttrium or other elements. While the operational voltage per cell can vary between about 2.4 and 3.8, the family still has a max of 4.2 and a minimum of about 2V per cell.




I've not used powerwholesale.? I used to import 10 Ah cylindrical cells from PSI in Taiwan.? I've used A123 cylindricals; Headway, PSI, Thundersky (thundersag...), CALB, and other prismatic LFPs. I've also used plenty of LCO pouches from Hobby King, both for RC and portable radios.? NiCd and NiMH before that.? My 5KW electric scooter/motorcycle was my primary vehicle and BMS test bed when I was building batteries.? It had a 21S pack of 60 Ah Thundersky LiFeYPO4 cells.? I have had good results from Docan Power and their Houston, TX warehouse.? They stock grade A and B cells from CALB, CATL (supplies VW), and EVE. DIYSolar and DIYElectricCar both have too much bad info. I prefer the signal to noise ratio of the Endless Sphere forum - more engineers and fewer "youtube influencers".

I appreciate your comments about your off grid battery.? While my battery business was tailored to ebikes, electric motorcycles, and the occasional plug-in Prius conversion, my personal goal was off-grid.? I'm a huge fan of the passive solar Earthship and have a complete solar and wind package (minus battery) for a future building.? While the energy demands for a passive solar building are about an order of magnitude lower than a conventional US single family house, my needs now that I'm living aboard a sailboat are down another order of magnitude.? My PV needs dropped from 3KW for the Earthship to 100W.? My current house battery is the battery I made for portable radio use - 2P4S 25 Ah LFP cells, a 100 A JBD BMS, and a 10A Genasun MPPT charge controller, all in a plastic 50 Cal ammo can.? I would have preferred to use a Stewart Pittaway DIYBMS, but didn't get it integrated in time before I put my lab into storage before the move. If one is a DIY type, it's really hard to beat the DIYBMS, especially if they use Victron balance of systems equipment.




Best, Andy
KG5RKP/MM


On Thu, Nov 24, 2022 at 09:05 AM, Jerry Gaffke wrote:
Andy,?
No real argument, I agree with most of what you say.

'Common usage' is a useful thing to be aware of, as this is how most other people describe
what they are doing, and even how manufacturers describe what they are selling.
In the world of lithium ion batteries, LiFePO4 chemistry is different enough that it is
necessary to call that out.? In particular, voltage per cell is different.? Everything else
often gets lumped together under the more generic term of lithium ion.

Some 15 years ago I bought a few raw pouch cells because they were cheap.
Big mistake.? If building a small battery pack, go with cylindrical cells like 18650's.
The pouch cells rupture easily and need far more physical protection.
You definitely want appropriate electrical protection circuitry.? If figuring all that out
does not sound fun, then buy a successful battery pack of some sort and use
the charging device that comes with it.? Could be borrowed from a shop tool,
an auto jump start device with a well protected low current port, or one of the
excellent Bioenno LiFePO4 batteries.

If building a big battery pack and you are interested in an educational project,
I can recommend the prisimatic LiFePO4 bricks from?? ?
Shipped from China, so may be tough to get if they go into lockdown again.
These have likely been passed over by electric vehicle manufacturers for
having specs somewhat out-of-family, but are relatively cheap.
Lots of even cheaper vendors on alibaba, but be careful as many are selling
used or damaged cells.? ?Good info on?https://diysolarforum.com

Being offgrid, there's a bank of 32 EVE LF280K cells in the basement powering
this conversation, configured as 2P16S, 29 kWh total, along with a JBD 200A BMS.

Jerry, KE7ER

On Thu, Nov 24, 2022 at 03:32 AM, AndyH wrote:
Yes, cobalt levels in some LiCoO variants are decreasing. The relative safety standings remain, however.?

? 'Common usage' isn't a useful metric. Folks interested in selecting a product within a family benefit from understanding when a disk ceramic doesn't replace an electrolytic, or why NP0 matters, right? Have you heard that nobody makes their own radios these days? hihi

? Metal cased cells are 'safer' only if one is working with individual cells and not a properly constructed battery. Anodes and cathodes need to be held together during charging and discharging. It's part of that 'safe if not abused or mishandled' thing.

? Look at how Tesla makes their reduced cobalt LiCoO batteries. Even though they start with metal cased cylindrical cells, they still have to encase them in fire retardant adhesives. In a crash they can still burn furiously and the fire can be difficult to extinguish.? (Sandy Munroe also shows how pouch cells are packaged into a proper battery.)




? Battery management chips are cheap these days, and one can purchase small battery management modules that provide cell balancing, charge and discharge current control, and cell-level high- and low-voltage protection while reporting battery health via low-power Bluetooth. Fun times to DIY batteries.

? 73, Andy

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