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Hello there! question about the group and about etching with naoh + hcl


 

Hi guys,

I wonder if this is same as the yahoo groups that have been ported? Anyways, I'm new to the list, Hi!

I watched the following video from nurdrage:

(10 etchants for pcb)

And I've settled to try with the one using naoh (he actually used bleach, but I have naoh at hand), and hcl. First because where I live hydrogen peroxide is expensive, second because I prefer mixing, using and disposing of, than storing, and third because I have easy access to the chemicals involved. I know the reaction produces Chlorine gas, though, but one offs is something I'm gonna have to live with.

He only mentions this method is not very efficient, which for me might be a pro, as I could control under etching better. My question is if anybody around has ever tried it and can tell me about timings, or any other related tips I should know before trying?

Thanks,


 

NaOH and HCL is just going to make salt water and some heat.? It's not going to be an etchant.


 

So how it comes you can see on the video it strips all the copper from it?

On 29/03/2019, designer_craig <cs6061@...> wrote:
NaOH and HCL is just going to make salt water and some heat.? It's not going
to be an etchant.




 

The homebrewpcbs group did migrate from Yahoo! to groups.io; welcome.

NaOH is not at all like bleach (NaOCl) - and I would not try anything that releases the Cl as a gas! It is very dangerous. There are many safer ways to etch copper. (If you think H2O2 is expensive, you should see what chemically burnt lungs or eyes cost!)

You might try NaCl (common table salt) and Hcl or NaCl and white vinegar (acetic acid) to start. A web search will get you started.

Donald.
--
*Plain Text* email -- it's an accessibility issue
() no proprietary attachments; no html mail
/\ <>

On 28-Mar-2019 17:13, Eduardo Costa wrote:
Hi guys,
I wonder if this is same as the yahoo groups that have been ported? Anyways, I'm new to the list, Hi!
I watched the following video from nurdrage:
(10 etchants for pcb)
And I've settled to try with the one using naoh (he actually used bleach, but I have naoh at hand), and hcl. First because where I live hydrogen peroxide is expensive, second because I prefer mixing, using and disposing of, than storing, and third because I have easy access to the chemicals involved. I know the reaction produces Chlorine gas, though, but one offs is something I'm gonna have to live with.
He only mentions this method is not very efficient, which for me might be a pro, as I could control under etching better. My question is if anybody around has ever tried it and can tell me about timings, or any other related tips I should know before trying?
Thanks,


 

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Eduardo,
I think the mix you are referring to in the video is the one that uses NaOCl which is sodium hypochlorite or common household? bleach.? This is NOT the same as NaOH which is sodium hydroxide or caustic soda.? Both are common household chemicals but are totally different.? NaOH and HCl will, as previously stated, simply make NaCl, common salt, and will have no etching action whatsoever.?


Sent from my Samsung Galaxy A5 (2017) on the Telstra Mobile Network

-------- Original message --------
From: Eduardo Costa <ecosta.tmp@...>
Date: 29/3/19 7:26 pm (GMT+10:00)
Subject: Re: [homebrewpcbs] Hello there! question about the group and about etching with naoh + hcl

So how it comes you can see on the video it strips all the copper from it?

On 29/03/2019, designer_craig <cs6061@...> wrote:
> NaOH and HCL is just going to make salt water and some heat.? It's not going
> to be an etchant.
>
>
>
>




 

Hey guys,

So I've mistaken sodium hypoclorite by naoh. I don't know why I was
sure bleach was naoh + water.

I'll first try nacl + hcl, as I know salt+vinegar it's just too slow.

Thanks so much for your help,

Regards,

On 29/03/2019, Andrew Love <alove@...> wrote:
Eduardo,I think the mix you are referring to in the video is the one that
uses NaOCl which is sodium hypochlorite or common household? bleach.? This
is NOT the same as NaOH which is sodium hydroxide or caustic soda.? Both are
common household chemicals but are totally different.? NaOH and HCl will, as
previously stated, simply make NaCl, common salt, and will have no etching
action whatsoever.?Sent from my Samsung Galaxy A5 (2017) on the Telstra
Mobile Network
-------- Original message --------From: Eduardo Costa <ecosta.tmp@...>
Date: 29/3/19 7:26 pm (GMT+10:00) To: [email protected] Subject: Re:
[homebrewpcbs] Hello there! question about the group and about etching with
naoh + hcl So how it comes you can see on the video it strips all the copper
from it?On 29/03/2019, designer_craig <cs6061@...> wrote:> NaOH and
HCL is just going to make salt water and some heat.? It's not going> to be
an etchant.>> >>



 

Been reading all this etching stuff for some time now.? Been doing it for 35 years now but have slowed down considerably doing it.? I don't have any problem etching boards, but drilling them is another matter.? If it's a simple circuit, NO PROBLEM!? But, any board needing many holes drilled is problematic for me.? I have a couple Dremel Tools plus a Dremel drill press.? That said, they must be out of round because the cost of broken drill bits using them on one board has become intolerable for me.? When finished, the cost of drills used up for one board is not worth.? So lately I have been using Proto Boards for the most part as all the holes are pre-drilled.? I don't know what all of you experience making your own boards but the drilling is my problem and not etching the thing!? Lastly, the Chinese will make you nice PC boards cheap if you can send them a GERBER File.? I'm now in the early stages in learning how to do this.? Then I'll be forever free of having to etch my own boards or drill them.? The cost of a Chinese board is cheaper then what I can make it for myself and will be plated, masked, silk screened and have plated through holes for multi layer boards.? The real cost to me will be learning how to use a CAD program.? I'm beyond doing most of this stuff myself.? Having it done today can be cheaper and better then home made.

Lee, w0vt

On 3/29/2019 12:22 PM, Eduardo Costa wrote:
Hey guys,

So I've mistaken sodium hypoclorite by naoh. I don't know why I was
sure bleach was naoh + water.

I'll first try nacl + hcl, as I know salt+vinegar it's just too slow.

Thanks so much for your help,

Regards,




On 29/03/2019, Andrew Love <alove@...> wrote:
Eduardo,I think the mix you are referring to in the video is the one that
uses NaOCl which is sodium hypochlorite or common household? bleach.? This
is NOT the same as NaOH which is sodium hydroxide or caustic soda.? Both are
common household chemicals but are totally different.? NaOH and HCl will, as
previously stated, simply make NaCl, common salt, and will have no etching
action whatsoever.?Sent from my Samsung Galaxy A5 (2017) on the Telstra
Mobile Network
-------- Original message --------From: Eduardo Costa <ecosta.tmp@...>
Date: 29/3/19 7:26 pm (GMT+10:00) To: [email protected] Subject: Re:
[homebrewpcbs] Hello there! question about the group and about etching with
naoh + hcl So how it comes you can see on the video it strips all the copper
from it?On 29/03/2019, designer_craig <cs6061@...> wrote:> NaOH and
HCL is just going to make salt water and some heat.? It's not going> to be
an etchant.>> >>



 

Don't overlook the cost of shipping and how soon you want them. If you are in the US you may find that for small boards (6 square inches or less) and a delivery time of 2 weeks some of the US manufacturers are fairly competitive in price.

Check: for some comparison prices.

?

Craig


On Fri, Mar 29, 2019 at 12:08 PM, Leland L. Bahr wrote:
Been reading all this etching stuff for some time now.? Been doing it
for 35 years now but have slowed down considerably doing it.? I don't
have any problem etching boards, but drilling them is another matter.?
If it's a simple circuit, NO PROBLEM!? But, any board needing many holes
drilled is problematic for me.? I have a couple Dremel Tools plus a
Dremel drill press.? That said, they must be out of round because the
cost of broken drill bits using them on one board has become intolerable
for me.? When finished, the cost of drills used up for one board is not
worth.? So lately I have been using Proto Boards for the most part as
all the holes are pre-drilled.? I don't know what all of you experience
making your own boards but the drilling is my problem and not etching
the thing!? Lastly, the Chinese will make you nice PC boards cheap if
you can send them a GERBER File.? I'm now in the early stages in
learning how to do this.? Then I'll be forever free of having to etch my
own boards or drill them.? The cost of a Chinese board is cheaper then
what I can make it for myself and will be plated, masked, silk screened
and have plated through holes for multi layer boards.? The real cost to
me will be learning how to use a CAD program.? I'm beyond doing most of
this stuff myself.? Having it done today can be cheaper and better then
home made.

Lee, w0vt


 

On Fri, 29 Mar 2019 13:03:24 -0500, you wrote:

Been reading all this etching stuff for some time now.? Been doing it
for 35 years now but have slowed down considerably doing it.? I don't
have any problem etching boards, but drilling them is another matter.?
If it's a simple circuit, NO PROBLEM!? But, any board needing many holes
drilled is problematic for me.?
I can understand that. At a minimum, you need a good drill press and
a too with very low runout.

I have a couple Dremel Tools plus a
Dremel drill press.? That said, they must be out of round because the
cost of broken drill bits using them on one board has become intolerable
for me.? When finished, the cost of drills used up for one board is not
worth.?
Dremels are not as precise as you'd like. They do have significant
runout, it's likely both the collet (aluminum) and the bearings. For
handheld work they are exactly at the right level of precision. For
drilling #76 holes with carbide bits.... I hope you don't mind buying
the bits in quantity lots.

I had a rather poor drill stand that I used with a dremel. I got
so-so results. I changed to a Proxxon drill. I found that the 12
volt version was satisfactory for PC boards up to about 1/8 inch
holes. At the top end, you'd like to use a regular drill press anyway
and hold the board down. Northward of a #42 drill, I didn't have any
problem hand holding the board. Southward of that, though, larger
holes were a problem.

Proxxon does have a drill press stand, I have no experience with it.

You could build something with parts intended for a 3D printer, the
rail extrusion, and the like. Not sure exactly how well it would
work, though. I haven't designed one.

There are such things as sensitive drill presses, designed for very
small drills, those could work. The problem with larger drill presses
is that they simply aren't fast enough. Spindle speed is too low.

I had a significant problem with parallax, so I was never quite sure
where the hole was to be drilled, and while the pad tends to help
center the drill, on a carbide drill and fast rpm, it doesn't.

I did do an upside down drill press, and so have others. You may find
the thread interesting.



So lately I have been using Proto Boards for the most part as
all the holes are pre-drilled.? I don't know what all of you experience
making your own boards but the drilling is my problem and not etching
the thing!?
I had that solved, so it went back to proper etching...

It just got too messy for me.

Lastly, the Chinese will make you nice PC boards cheap if
you can send them a GERBER File.?
Frequently easy to make in an automated manner.

I'm now in the early stages in
learning how to do this.? Then I'll be forever free of having to etch my
own boards or drill them.? The cost of a Chinese board is cheaper then
what I can make it for myself and will be plated, masked, silk screened
and have plated through holes for multi layer boards.? The real cost to
me will be learning how to use a CAD program.? I'm beyond doing most of
this stuff myself.? Having it done today can be cheaper and better then
home made.
As in previous posts, I found that the precision needed for making the
complex boards that I designed was beyond (or getting there) my
capabilities. Wire stitching top and bottom layers can't be done
under a surface mount part.

As for CAD programs.

There are many. Check to see what the limitations are in board size
or complexity depending on whether or not they're paid or free
versions, or only free versions.

As an example, EAGLE is free for up to 3 x 4 inch boards, and then
goes to a subscription model on a per month basis. From Eagle, the
chinese PC board fabricators I use (seeedstudio.com) have a script
that you can run with a button click that produces the exact gerbers
that they need.

Other programs (I suspect KiCAD here) can do the same thing, and I
think that they have a script for KiCad.

You would, of course, want a program that is intended for PC board
design, simply because it links schematic to board. It will cut down
possible errors. Always remember to run rule checks especially before
going to any production step. Been bitten there at times.

Certain overlap errors are just fine, such as a part that comes in a
standard or wide package, and you decide to have both, allowing one
to sit on the other's footprint. Naturally, you only use one at a
time, but the pads overlap. While your program will flag an error,
the board makers don't care.

Harvey



Lee, w0vt

On 3/29/2019 12:22 PM, Eduardo Costa wrote:
Hey guys,

So I've mistaken sodium hypoclorite by naoh. I don't know why I was
sure bleach was naoh + water.

I'll first try nacl + hcl, as I know salt+vinegar it's just too slow.

Thanks so much for your help,

Regards,




On 29/03/2019, Andrew Love <alove@...> wrote:
Eduardo,I think the mix you are referring to in the video is the one that
uses NaOCl which is sodium hypochlorite or common household? bleach.? This
is NOT the same as NaOH which is sodium hydroxide or caustic soda.? Both are
common household chemicals but are totally different.? NaOH and HCl will, as
previously stated, simply make NaCl, common salt, and will have no etching
action whatsoever.?Sent from my Samsung Galaxy A5 (2017) on the Telstra
Mobile Network
-------- Original message --------From: Eduardo Costa <ecosta.tmp@...>
Date: 29/3/19 7:26 pm (GMT+10:00) To: [email protected] Subject: Re:
[homebrewpcbs] Hello there! question about the group and about etching with
naoh + hcl So how it comes you can see on the video it strips all the copper
from it?On 29/03/2019, designer_craig <cs6061@...> wrote:> NaOH and
HCL is just going to make salt water and some heat.? It's not going> to be
an etchant.>> >>





 

Instead, try to use hcl and hydrogen peroxide
?Most industry guys are using this combination

Sarma? ?vu3zmv

On Fri, 29 Mar 2019, 10:52 pm Eduardo Costa <ecosta.tmp@... wrote:
Hey guys,

So I've mistaken sodium hypoclorite by naoh. I don't know why I was
sure bleach was naoh + water.

I'll first try nacl + hcl, as I know salt+vinegar it's just too slow.

Thanks so much for your help,

Regards,




On 29/03/2019, Andrew Love <alove@...> wrote:
> Eduardo,I think the mix you are referring to in the video is the one that
> uses NaOCl which is sodium hypochlorite or common household? bleach.? This
> is NOT the same as NaOH which is sodium hydroxide or caustic soda.? Both are
> common household chemicals but are totally different.? NaOH and HCl will, as
> previously stated, simply make NaCl, common salt, and will have no etching
> action whatsoever.?Sent from my Samsung Galaxy A5 (2017) on the Telstra
> Mobile Network
> -------- Original message --------From: Eduardo Costa <ecosta.tmp@...>
> Date: 29/3/19? 7:26 pm? (GMT+10:00) To: [email protected] Subject: Re:
> [homebrewpcbs] Hello there! question about the group and about etching with
> naoh + hcl So how it comes you can see on the video it strips all the copper
> from it?On 29/03/2019, designer_craig <cs6061@...> wrote:> NaOH and
> HCL is just going to make salt water and some heat.? It's not going> to be
> an etchant.>> >>
>
>
>




 

You can get spindles cheap these days, eg

R11-3-175mm-52mm-mounting-bracket-fixture-ER11/32868952490.html

This is what all those little CNC engraving routers use.

Possibly a bit heavy to bolt onto your average 3D printer. You can also buy
just the collet assembly if you've a suitable motor in your junk pile.

Tony

I have a couple Dremel Tools plus a
Dremel drill press.? That said, they must be out of round because the
cost of broken drill bits using them on one board has become intolerable
for me.? When finished, the cost of drills used up for one board is not
worth.
Dremels are not as precise as you'd like. They do have significant
runout, it's likely both the collet (aluminum) and the bearings. For
handheld work they are exactly at the right level of precision. For
drilling #76 holes with carbide bits.... I hope you don't mind buying
the bits in quantity lots.

I had a rather poor drill stand that I used with a dremel. I got
so-so results. I changed to a Proxxon drill. I found that the 12
volt version was satisfactory for PC boards up to about 1/8 inch
holes. At the top end, you'd like to use a regular drill press anyway
and hold the board down. Northward of a #42 drill, I didn't have any
problem hand holding the board. Southward of that, though, larger
holes were a problem.

Proxxon does have a drill press stand, I have no experience with it.

You could build something with parts intended for a 3D printer, the
rail extrusion, and the like. Not sure exactly how well it would
work, though. I haven't designed one.

There are such things as sensitive drill presses, designed for very
small drills, those could work. The problem with larger drill presses
is that they simply aren't fast enough. Spindle speed is too low.

I had a significant problem with parallax, so I was never quite sure
where the hole was to be drilled, and while the pad tends to help
center the drill, on a carbide drill and fast rpm, it doesn't.

I did do an upside down drill press, and so have others. You may find
the thread interesting.


 

Re-posting with an unbroken? link: <>

If this didn't work, just paste all the bits from " to ".html" into one link.

Donald.
--
*Plain Text* email -- it's an accessibility issue
() no proprietary attachments; no html mail
/\ <>

On 2019-03-31 2:57 p.m., Tony Smith wrote:
You can get spindles cheap these days, eg

R11-3-175mm-52mm-mounting-bracket-fixture-ER11/32868952490.html
This is what all those little CNC engraving routers use.
Possibly a bit heavy to bolt onto your average 3D printer. You can also buy
just the collet assembly if you've a suitable motor in your junk pile.
Tony

I have a couple Dremel Tools plus a
Dremel drill press.? That said, they must be out of round because the
cost of broken drill bits using them on one board has become intolerable
for me.? When finished, the cost of drills used up for one board is not
worth.
Dremels are not as precise as you'd like. They do have significant
runout, it's likely both the collet (aluminum) and the bearings. For
handheld work they are exactly at the right level of precision. For
drilling #76 holes with carbide bits.... I hope you don't mind buying
the bits in quantity lots.

I had a rather poor drill stand that I used with a dremel. I got
so-so results. I changed to a Proxxon drill. I found that the 12
volt version was satisfactory for PC boards up to about 1/8 inch
holes. At the top end, you'd like to use a regular drill press anyway
and hold the board down. Northward of a #42 drill, I didn't have any
problem hand holding the board. Southward of that, though, larger
holes were a problem.

Proxxon does have a drill press stand, I have no experience with it.

You could build something with parts intended for a 3D printer, the
rail extrusion, and the like. Not sure exactly how well it would
work, though. I haven't designed one.

There are such things as sensitive drill presses, designed for very
small drills, those could work. The problem with larger drill presses
is that they simply aren't fast enough. Spindle speed is too low.

I had a significant problem with parallax, so I was never quite sure
where the hole was to be drilled, and while the pad tends to help
center the drill, on a carbide drill and fast rpm, it doesn't.

I did do an upside down drill press, and so have others. You may find
the thread interesting.


 

Hello,

I always use hydrochloric acid and hydrogen peroxide; it is much cleaner than ferric chloride. The solution can be reused multiple times; so it does not have to be discarded after use. As the solution gets old, the hydrogen peroxide will be used up and the solution will turn black (if there is enough copper in it). Adding some peroxide will make it turn transparent green again and etching continues. Acid may be added as it gets old as well. I usually don't heat the solution, but rock the plastic container up and down to move the solution over the PCB. I guess the reaction is somewhat exothermic.. Spraying or bubble agitation would speed the process much, of course; but even with agitation by rocking, copper removal? from the surface is visible - the color of the etched areas change.. Peroxide oxidises the surface before the acid removes it, as much as I know.

If I remember right, the formula was 330ml. (cc) HCl plus 70ml. (cc) Hydrogen Peroxide - and the rest water to make one liter, both chemicals concentrated. The mixture is not critical, but if too much peroxide is used? there will be gassing and the bottle cap may be thrown off when in storage - it happened to me..?

If an iron part is immersed in the much used solution, copper gets plated on the iron, so this may be a way of recuperating copper as well..

If the used solution will be saved, one has to be careful and save it in a glass container with a plastic cap - out of reach of children, etc. I also don't know if the chemicals are easy to procure and keep - I used to get them from my workplace. We had a prototype PCB lab (from Think Tinker USA) for single and double sided PCBs, including through hole plating. At home I mostly printed single sided boards, using Positiv20 resist.

Bulent Mutlugil, PhD
Ankara Turkey