After more time has passed, noted in the parameter bar on the right, in seconds, the next peaks coincide.?
These are in the U and Np L shell peak trio at the left end, corresponding to Am-241 decay product Np-137 La, Lb and Lg X-Rays and very near but not overlapping, Uranium's La-Lb-Lg X-Rays.
The Np peaks are a given, when you have a predominant 59.5, there will 100% of decays be Np daughter and the yield of the Np-X-ray as well as the variety of Gamma Rays is well documented.

Note that the Am-241 peak at 59.5 has not balanced yet. This is important being part of the proof that the U-Np L shell X-Ray peaks truly do contain more than just Np contribution. Where do the Uranium peaks come from? Remember, the daughter element is where the X-Rays come from. What is making fresh Uranium in here? One path is by XRF of old Uranium, the other is the formation of new U-234 in the U-238 decay chain, and the 3rd most obvious way is decay of Plutonium isotopes into Uranium atoms.
We know there is or at least was Plutonium present in these samples. Am-241 is the daughter of Pu-241, the only common long lived Pu isotope to beta decay. The others decay by alpha particle and lead directly to one of several Uranium daughters. and those of course will have U X-Rays
Notice too the Pb/Bi X-Rays (La-Lb) ~72-85 keV . This opens a whole new discussion avenue concerning lower daughters.
Geo>K0ff